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What Is Ambien Zolpidem is an opiate, also called a narcotic. It affects chemicals in the brain that may be unstable in people with sleep problems ( wakefulness).  Zolpidem is used to treat wakefulness. The immediate-release forms are Ambien, Intermezzo, Edluar, and Zolpimist, which are used to help you fall asleep. The extended-release form of zolpidem is Ambien CRwhich has a first subcaste that dissolves snappily to help you fall asleep, and an alternate subcaste that dissolves sluggishly to help you stay asleep. Am... more